Solution is correct but should be written in the form
$$
u=\left\{\begin{aligned}
& ...... && \text{case 1},\\
& ...... && \text{case 2}
\end{aligned}\right.
$$
where "case 1" and "case 2" (or may be more cases?) should be described.
So that anyone could easily compare what he or she got with yours. I actually highlighted cases in your posts.
Solution
From (\ref{1-1}):
\begin{equation}
u(x,t)=\phi (x+4t)+\psi (x-4t).
\label{1-5}
\end{equation}
Plugging to (\ref{1-2})--(\ref{1-3}), we conclude that for $x>0$ $\phi(x) +\psi(x)=4e^{-2x}$, $4 \phi'(x)-4\psi'(x)=16e^{-2x}$; integrating the second equation we get $\phi (x)-\psi(x)=-2e^{-2x}$ (since we can select constant equal to $0$ here) and finally
\begin{equation}
\phi(x)=e^{-2x}, \quad \psi(x)=3e^{-2x}\qquad \text{for } x>0.
\label{1-6}
\end{equation}
We need to find $\psi(x)$ for $x<0$. Plugging (\ref{1-5}) into (\ref{1-4}) we conclude that
\begin{align*}
&&&\phi'(4t)-\phi(4t)+\psi'(-4t)-\psi(-4t)= e^{-8t}\qquad\text{for }t>0,\iff\\
&&&\psi'(-4t)-\psi(-4t)=4e^{-8t},\\
&\text{and plugging $x=-4t$ we see that}\\
&&&\psi'(x)-\psi(x)=4e^{2x}\qquad\text{for }x<0,\\
&\text{and solving this ODE}\\
&&&(\psi e^{-x})'= 4e^{x}\implies \psi(x) e^{-x}=4e^{x}+C
\end{align*}
and therefore $\psi(x)=4e^{2x}+Ce^{x}$ for $x<0$. Since $\psi(+0)=3$, $\psi(-0)=4+C$ we need for continuity $C=-1$. So
\begin{equation}
\psi(x)=4e^{2x}-e^{x}\qquad \text{for } x>0.
\label{1-7}
\end{equation}
Finally,
\begin{equation}
u(x,t)= \left\{\begin{aligned}
&e^{-2x-8t}+3e^{-2x+8t} \qquad &&x>4t>0,\\
&e^{-2x-8t} + 4e^{2x-8t}-e^{x-4t} &&0<x< 4t.
\end{aligned}\right.
\end{equation}
Comments
Almost everybody got correctly $\phi(x),\psi(x)$ for $x>0$ and $u(x,t)$ for $x>4t$.
Most correctly wrote equation $\psi' -\psi =4e^{2x}$ for $x<0$.
But then correctly finding one solution $\psi= 4e^{2x}$ (mostly by the method of undetermined coefficient), they wrote $\psi=4e^{2x}+C$ rather than $\psi=4e^{2x}+Ce^{x}$ (WTH). Which in turn yielded term $-1$ instead of correct one $-e^{x-4t}$ in the very end for $0<x<4t$.